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function my_help_link(){
  ?>
  <li><a href="http://someplace.org">Help</a>

  <ul class="your-ul-list-css-classname">
  <li><a href="http://someplace.org">Help 1</a></li>
  <li class="alt"><a href="http://someplace.org">Help 2</a></li>
  <li><a href="http://someplace.org">Help 3</a></li>
  <li class="alt"><a href="http://someplace.org">Help 4</a></li>
  <li><a href="http://someplace.org">Help 5</a></li>
  </ul>

  </li>
  <?php
}
add_action( 'bp_adminbar_menus', 'my_help_link', 14 );